You can do a lot with acrylic and few tools. If you’re just starting out we’d suggest taking a look at [Michael Colombo’s] guide to heating, bending, and gluing to create custom acrylic enclosures.
Plywood is an interesting material: made up of many layers of thin wood plys, it can be built up into elegantly curved shapes. Do you need to limit it to just wood, though? [Zach of All Trades] has ...